CHARACTERISTIC OF THE METAL POLYMERS STRUCTURE AT THE SUPERMOLECULAR LEVEL OF THE ORGANIZATION

  • E. О. Pashchenko Bakul Institute for superhard materials NAS of Ukraine https://orcid.org/0000-0001-5545-5780
  • D. О. Savchenko Bakul Institute for superhard materials NAS of Ukraine https://orcid.org/0000-0002-9474-3993
  • S. А. Kukharenko Bakul Institute for superhard materials NAS of Ukraine https://orcid.org/0000-0001-5256-480X
  • V. М. Bychyhin Bakul Institute for superhard materials NAS of Ukraine
  • O. M. Koshkin Bakul Institute for superhard materials NAS of Ukraine
  • A. G. Dovgan Bakul Institute for superhard materials NAS of Ukraine
  • I. V. Leshchuk Bakul Institute for superhard materials NAS of Ukraine
  • O. V. Lazhevska Bakul Institute for superhard materials NAS of Ukraine
Keywords: cross-linked polymer, metalloligomer; oligophenolates of vanadium, iron, copper; polymerization temperature and pressure; sections of graphene-graphane structures

Abstract

The processes of three-dimensional cross-linked polymers formation of a hybrid nature have been investigated and it has been found that the obtained spatially cross-linked polymers have a layered structure that combines planar fragments of condensed aromatic nuclei and sections of graphene-graphane structures. The obtained oligomers have a set of promising characteristics for their use as heat-resistant polymer binders, in particular, for the manufacture of high-strength composites reinforced with carbon fibers and fabrics.

Published
2022-02-11
Section
Development and implementation of equipment and tools equipped with hard alloys